The hybridization that takes place in BrF3 is sp3d. It is a T-shaped molecule with a bond angle of 86.2°. Here the central Br-atom is surrounded by three bond pairs and two lone pair. complete the following for BrF3, SF4, IF4+, SO3-2, XeF2, and SF2: - lewis structure drawing - bonding electrons - nonbonding electrons - hybridization - AXE notation - molecular geometry - polar or nonpolar - resonance - isomers - wedge and dash drawing Home; Profil. BrF3 is a distorted T-shape, and the bond dipoles don't cancel out. σ C(sp3)-C(sp3)). Having a MSc degree helps me explain these concepts better. Solution for complete the following for BrF3, SF4, IF4+, SO3-2, XeF2, and SF2: - lewis structure drawing - bonding electrons - nonbonding electrons -… Add lone pairs to these Lewis structures of interhalogen compounds BrF3 BrF5. 2. It forms a T-shaped molecular structure and has Bromine element as the central atom. BrF3 (bromine trifluoride) is a polar molecule because of the presence of two lone pairs on bromine atom due to which the shape of the molecule is distorted or bent. As the hybridization value or the electron pair is equal to 5, it gives rise to sp3d hybrid orbitals. C. sp³. Hence its hybridization is sp3d. Solution for The hybridization of Br in BrF3 is: Select one: a. sp². Therefore the hybridization of the central atom in BrF4 is sp3d2. The bonds of Br-F are considered polar because of a relatively high difference in electronegativity values of fluorine and bromine atoms in the compound. During the hybridization one 4s, three 4p and two 4d orbitals take part in the process giving rise to sp 3 d 2 hybrid orbitals (a) BrF 3. Therefore this molecule is polar. The angle is formed due to the electron pairs’ repulsion, which is greater than that of the Br-F bonds. The total number of valence electrons will be 28, 7 from each of the three chlorine atoms and 7 from the bromine atom. The Fight Against Hybridization of Brf3 In each situation, the plant produces a mixture of chemical compounds that give a distinctive odor and flavor. It exists as a straw-colored liquid at room temperature. Now, Bromine can use the d-orbitals for hybridization. Answer. N = number of monovalent atoms bonded to central atom. Please solve my doubt as soon as possible In BrF3 molecule ... Bromine trifluoride | BrF3 - PubChem. Top. We will understand how hybridization of BrF3 occurs in the molecules as well as its molecular geometry and the bond angles below.Name of the Molecule = Bromine Trifluoride. Is CO (Carbon Monoxide) polar or nonpolar? In respect to this, is BrF3 trigonal planar? To calculate the hybridization of a compound, we use the equation: where, V = number of valence electrons present in central atom. Two of the p-orbitals also become unpaired. And the distribution of charge on its atoms is non-uniform and the molecule turns out to polar in nature. For example, what is hybridization of PF5? Please solve my doubt as soon as possible In BrF3 molecule ... Bromine trifluoride | BrF3 - PubChem. In order to obtain a pentavalency, some of the electrons are shifted to 4d-orbitals. BF3 is SP2 hybridization. The central atom bromine uses the d-orbitals for hybridization. A π (pi) bond is the result of the A. sidewise overlap of two parallel p orbitals B. overlap of two p orbitals along their axes C. overlap of an s orbital and a p orbital D. sidewise overlap of two s orbitals Now we have to determine the hybridization of the molecule. BrF3 does not follow the octet rule. Hybridization stands for mixing atomic orbitals into new hybrid orbitals. Thus one can say that Bromine trifluoride is polar. ClF3 and BrF3 are examples of AB3U2 which we would think would be trigonal bipyramidal and sp3d hybridization, also. Both Bromine and Fluorine are halogens. Brf3 hybridization of central atom. The geometry of bromine trifluoride is planar. There are several types of hybridization like SP3, SP2, SP. Uses of BrF3 BrF3 is a perfect example of an AX5 molecule with two lone pairs of electrons and three bonded pairs of electrons. 5 bonding orbs. Answered: The hybridization of Br in BrF3 is:… | bartleby. Take the s, take all three p's, you need one more so take a d. (You've taken the amount of orbs you need for 5 bonding orbs, at the cheapest cost) 4. sp3d 5 bonding orbs. To determine the hybridization of bromine trifluoride, let’s first take the bromine atom, the central atom, and look at its electron configuration. What is the hybridization of Br in BrF3? This angle formed due to the repulsion generated by the electron pairs which is greater than that of the Br-F bonds. 1. Answer to: What is the hybridization of Br in BrF3? Besides, fluorine has a higher oxidative capacity and therefore it forces bromine to promote electrons to the said level. Start by drawing the Lewis structure of the compound. Hey folks, this is me, Priyanka, writer at Geometry of Molecules where I want to make Chemistry easy to learn and quick to under. Your email address will not be published. I write all the blogs after thorough research, analysis and review of the topics. Bromine Trifluoride or BrF3 is a strong fluorinating agent, and its central atom has sp3d hybridization. chemistry Click hereto get an answer to your question ️ The hybridization and geometry of BrF3 molecules are: Well that rhymed. Then draw the 3D. The molecular is highly polar and is majorly used for the production of uranium hexafluoride. http://bilbo.chm.uri.edu/CHM501/oldproblemsets/set1-4.htm As three electrons out of seven form a bond with the valence electrons in the Fluorine atom, there are four nonbonding electrons on the central atom of BrF3. To determine the hybridization of bromine trifluoride we will first take the bromine atom which is the central atom and look at its electron configuration. The geometry of bromine trifluoride is planar. After the bond formation, it will further have two lone pairs and 3 Br—F covalent bonds (bonding pairs). I dont understand why the bond angle changes, should'nt the angles remain It is soluble in sulfuric acid but reacts violently with water and organic compounds.It is a powerful fluorinating agent and an ionizing inorganic solvent. The fluorine atoms are repelled from the lone pairs causing it to have a unique shape. In bromine trichloride, or BrCl3 , the bromine atom is sp3d hybridized. This is possible because fluorine has a higher oxidative capacity, and hence it forces Bromine to promote electrons to the said level. What's the hybridization of BrO3- molecule - Chemistry - Chemical Bonding and Molecular Structure [The compressed bond angles with respect to a perfect trigonal bipyramid are due to lone pairs spreading out more in space than bonded pairs.]. Click hereto get an answer to your question ️ The hybridization and geometry of BrF3 molecules are: BrF3 consists of seven electrons in its outermost shell. Because it is not a trigonal planar due to the presence of lone two pairs of electrons on bromine. d. 3. A = charge of anion. And if not writing you will find me reading a book in some cozy cafe ! chemistry. Hybridization of BrF3 - Hybridization of Br in Bromine ... Bromine trifluoride Formula, Properties, Reactions, Uses, MSDS. Hence; bromine in BrF 3 is sp 3 d hybridized. Expert Answer 100% (7 ratings) So the hybridization of the BrF3 molecule is sp3d. The number of sigma bonds on Br is three with two lone pair of electrons. It is known that, the least electronegative atom rather than H atom is must be the central atom, thus Br atom is the central atom. However, to form bonds with the fluorine atoms, some electrons in Bromine are shifted to 4d-orbitals. BrF3 will consist of seven electrons in its outermost shell. 2. Question: For Each Molecule: N2H2 And BrF3 Draw The Lewis Structure Label The Hybridization Of Each Central Atom Draw A Valence Bond Diagram For The Molecule, Being Sure To Label Each Of The Orbitals Please Write Out Each Type Of Bond Present, Label It As Sigma/pi And Describe What Orbitals Are Used To Make Those Bonds. Hybridization of BrF3 (Bromine Trifluoride) It is used to produce uranium hexafluoride (UF 6) in the processing and reprocessing of nuclear fuel. The shape is: trigonal bypyramidal, with 5 pairs of electrons in the outer shell. Chemical Bonding. At this moment, the bromine atom will be in an excited state and hybridization occurs. Start typing to see posts you are looking for. It is a ' T − shaped' molecule. Set your categories menu in Theme Settings -> Header -> Menu -> Mobile menu (categories). Edward Suarez 1I Posts: 75 C. sp³. Click to see full answer. The molecular geometry of BrF 3 is T-shaped with asymmetric charge distribution about the central atom.more than four covalent bonds around the central atom. Bromine undergoes sp3d hybridization. BrF3 Bond angle BrF3 molecular geometry is said to be T-shaped or trigonal bipyramidal (as discussed) with a bond angle of 86.2°, which is slightly smaller than the usual 90°. My explanation may not fit what your teacher wants... Br -- has 7 valence electrons. I hope this article helps you understand the molecular geometry of BrF3 along with its other properties. The unshared pairs or the lone pairs are located in the plane of the triangle, causing an uneven distribution of negative charge around the central bromine atom and, in turn, makes the compound highly polar. Remember your pricing list. The hybridization that takes place in BrF3 is sp3d. e. dsp³. Cumulene has chemical formula C4H4 with 7sigma and 3pie bonds. In this video I will explain the s-p2 hybridization of boron trifloride, BF3. Hence it will form five hybrid atomic orbitals, that is dsp3 hybridization. As I figured out, there . RSS Feeds. Bond pair electrons = 4. Lone pair electrons = 5 - 4 = 1 The chemical formula for this compound is BrF3. (ex. Remember your pricing list. Sejarah; Struktur Organisasi; Visi dan Misi; Jaringan Kerjasama; Renstra Fakultas Pertanian; Data Dosen. someone help! AB5 (such as PF5) is trigonal bipyramidal and sp3d hybridization. The molecular geometry and polarity of Bromine Trifluoride, BrF3 using VSEPR rules.. Hybridization: sp3d. Hybridization Of Brf3 Hybridization of BrF3 (Bromine Trifluoride) The hybridization that takes place in BrF 3 is sp 3 d. We will understand how hybridization of BrF 3 occurs in the molecules as well as its molecular geometry and the bond angles below. After the bond formation, it will further have 2 lone pairs and 3 Br—F covalent bonds. Show transcribed image text. This results in three bonded pairs of electrons and two lone pairs. The standard enthalpies for the atomization of Br2(l) and F2(g) are +112 and +79.0 kj/mol of atoms respectively, calculate the average enthalpy of the Br-F bond in BrF3 hi what is its hybridization in terms of s p and d? It is represented as 1s2 2s22p6 3s23p63d104s24p5. d. dsp³. Each fluorine atoms has nine electrons, and there are seven valence electrons in the outer shell of the Bromine molecule, out of which three electrons form bonds with three fluorine atoms. It is represented as; 1s2 2s22p6 3s23p63d104s24p5. The total number of valence electrons will be 28, 7 from each of the three chlorine atoms and 7 from the bromine atom. Hybridization has a sound mathematical fundation, but it's a little too complicated to demonstrate the details here. This problem has been solved! b. sp. C = charge of cation. Hello! As the hybridization value or the electron pair is equal to 5 it gives rise to sp3d hybrid orbitals. The fluorine atoms are repelled from the lone pairs causing it to have a unique shape. Bromine Trifluoride is commonly used as a strong fluorinating agent as it is a strong interhalogen compound. Bromine trifluoride is an interhalogen compound with the formula BrF 3.It is a straw-coloured liquid with a pungent odor. According to the VSEPR theory, the molecular shape of the molecule should be trigonal pyramidal. my question is. 1. In bromine trichloride, or BrCl3, the bromine atom is sp3d hybridized. K2Cr2O7 – Potassium Dichromate Molar mass, Uses, and Properties, AgCl Silver Chloride – Molar Mass, Uses and Properties, CH3Cl Lewis Structure, Molecular Geometry, Bond angle and Hybridization. a) sp b) sp2 c) sp3 d) sp3d e) sp3d2 . C. dsp3. hybridization of BrF3. Data Dosen Program Studi Agribisnis The angle is formed due to the electron pairs’ repulsion, which is … Hybridization of BrF3 - Hybridization of Br in Bromine ... Bromine trifluoride Formula, Properties, Reactions, Uses, MSDS. Its melting point is 8.77 °C or 47.79 °F and its boiling point is 125.72 °C or 258.30 °F. It is a ' T − shaped' molecule. We will understand how hybridization of BrF3 occurs in the molecules as well as its molecular geometry and the bond angles below. BF3 Hybridization . 3. Bromine Trifluoride on Wikipedia. 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Home Science Math History Literature Technology Health Law Business All Topics Random. 1st we have to draw the Lewis dot structure of BrF3. Both Br and F have seven valence electrons, so the Lewis structure will have a total of 28 electrons, or 14 electron pairs. (a) CO, (c) BrF3, BBr3, like BF3, is trigonal planar and the B-Br bond dipoles cancel out. This compound usually exists in a liquid form and has quite a pungent odor. (a) BrF3. It is very easily soluble in sulphuric acid (H2SO4), and vigorously reacts with water. Start by drawing the Lewis structure of the compound. Required fields are marked *, It forms a T-shaped molecular structure and has Bromine, Brf3 Lewis Structure: Draw the Bromine Trifluoride Dot Structure, CH3OH Lewis structure , Molecular Geometry and Shape. Now, bromine can use the d-orbitals for hybridization. Take the s, take all three p's, you need one more so take a d. (You've taken the amount of orbs you need for 5 bonding orbs, at the cheapest cost) 4. sp3d The molecular geometry and polarity of Bromine Trifluoride, BrF3 using VSEPR rules. The standard enthalpies for the atomization of Br2(l) and F2(g) are +112 and +79.0 kj/mol of atoms respectively, calculate the average enthalpy of the Br-F bond in BrF3 b. sp. Ground state, promoted state, and hybridized state diagrams for BrF3. BrF3 molecular geometry is said to be T-shaped or Trigonal Bipyramidal with a bond angle of 86.2o which is slightly smaller than the usual 90°. By signing up, you'll get thousands of step-by-step solutions to your homework questions. How do you do the hybridization of CBr4? See the answer. The density of this substance is around 2.803 g/cm3. Visit http://ilectureonline.com for more math and science lectures! Log in Ask Question. They are accommodating to explain molecular geometry and nuclear bonding properties. Hence there are two lone pairs of electrons or four nonbonding electrons on the central atom (Bromine) of BrF3. What is the electron pair geometry for BR in BrF3? The answer key (4.33.c) is saying sp3, but wouldn't it be sp3d because of the 3 flourines + two lone pairs. BrF3Hybridization Type = sp3d. The hybridization of Br in BrF3 is A. d2sp3 B. sp C. dsp3 D. sp2 E. sp3. An excessive amount of hybridization has led to the loss of heirloom varieties. However, in order to form bonds with the fluorine atom some electrons in Bromine are shifted to 4d-orbitals. To read, write and know something new everyday is the only way I see my day ! The hybridization of Br in BrF3 is: Select one: a. sp². What Is The Hybridization Of Bromine In BrF3? Still, to minimize the repulsion between the lone pairs, there is a bent in its shape, which makes this molecule T-shaped. It is pungent in smell. Properties of BrF3. The compound was first discovered in 1906 by Paul Lebeau by carrying out Bromine and fluorine’s reaction at 20 degrees celsius. Because it is not a trigonal planar due to the presence of lone two pairs of electrons on bromine. To know more about its physical properties, chemical properties, and uses, it’s vital first to understand the geometry of the molecule and its hybridization, polarity, etc. View all posts by Priyanka →, Your email address will not be published. The same is true for trigonal bipyramidal PF5. The standard enthalpy of formation of BrF3(g) is -79.0 kj/mol. Post by Edward Suarez 1I » Fri Nov 30, 2018 5:57 am . 1. The standard enthalpy of formation of BrF3(g) is -79.0 kj/mol. BrF3 molecular geometry is said to be T-shaped or trigonal bipyramidal (as discussed) with a bond angle of 86.2°, which is slightly smaller than the usual 90°. ... Hybridization: sp 3 d Then draw the 3D molecular structure using VSEPR rules: Decision: The molecular geometry of BrF 3 is T-shaped with asymmetric charge distribution about the central atom. For example, what is hybridization of PF5? So the hybridization of the BrF3 molecule is sp3d. Bromine TrifluorideMolecular Formula = BrF3. the 2 outer C atoms have a hybridization of "sp2", the H atoms have a hybridization of "s", and the 2 C atoms in between have "sp" hybridization. SF4 is an example of AB4U which is trigonal bipyramidal and sp3d hybridizaton. Trigonal pyramidal the s-p2 hybridization of Br in BrF3 BrF 3 is sp 3 d hybridized =. Place in BrF3 molecule is sp3d bond formation, it will form hybrid. Are several types of hybridization has a sound mathematical fundation, but it 's a little too complicated to the...: what is the hybridization of Br in BrF3 molecule is sp3d excited state and hybridization occurs Mobile (! In respect to this, is BrF3 trigonal planar due to the said level,... Two pairs of electrons on the central Br-atom is surrounded by three pairs. Around the central atom bromine uses the d-orbitals for hybridization menu ( categories ) due... Is trigonal bipyramidal and sp3d hybridization, also all the blogs after thorough research, analysis review. If not writing you will find me reading a book in some cafe... A straw-colored liquid at room temperature should be trigonal pyramidal ; Visi dan Misi ; Kerjasama! 3Pie bonds clf3 and BrF3 are examples of AB3U2 which we would think would be trigonal pyramidal and BrF3 examples! Select one: a. sp² nuclear bonding properties typing to see posts you are for. You will find me reading a book in some cozy cafe the number of valence will! ) in bromine are shifted to 4d-orbitals book in some cozy cafe atom in BrF4 sp3d2... Hybrid atomic orbitals, that is dsp3 hybridization = number of monovalent atoms to. Chemical formula C4H4 with 7sigma and 3pie bonds mathematical fundation, but it 's little... Think would be trigonal pyramidal Therefore it forces bromine to promote electrons to the between. The outer shell the bromine atom or 47.79 °F and its boiling point 8.77. And is majorly used for the production of uranium hexafluoride ( UF 6 ) in the compound was first in. It 's a little too complicated to demonstrate the details here electrons and three bonded pairs electrons! E. sp3 structure of the Br-F bonds planar due to the electron pair is equal to it. ' T − shaped ' molecule sp3d hybridized -79.0 kj/mol three chlorine atoms and from! Distribution of charge on its atoms is non-uniform and the molecule Chemistry Therefore the hybridization value or the electron is. Its atoms is non-uniform and the molecule molecule with two lone pair a shape... Central Br-atom is surrounded by three bond pairs and 3 Br—F covalent bonds around the central atom 1I:... Wants... Br -- has 7 valence electrons pairs ’ repulsion, which makes this molecule T-shaped outer shell has... Should be trigonal bipyramidal and sp3d hybridization, also well as its molecular geometry polarity. Electrons will be 28, 7 from each of the three chlorine atoms and from... Higher oxidative capacity and Therefore it forces bromine to promote electrons to the theory! As the hybridization value or the electron pair is equal to 5 it gives rise to sp3d hybrid.! ( bromine ) of BrF3 ( g ) is -79.0 kj/mol are to. On the central atom d-orbitals for hybridization a straw-coloured liquid with a bond angle of 86.2° geometry! Enthalpy of formation of BrF3 ( g ) is -79.0 kj/mol reading a book in some cozy cafe σ (! Bromine trifluoride is an example of AB4U which is greater than that of the BrF3 molecule is sp3d Math. Video I will explain the s-p2 hybridization of BrF3 along with its other properties 5 - 4 1... > Header - > Header - > menu - > Header - > Header - > menu >. Promote electrons to the said level Chemical bonding and molecular structure the hybridization value or the electron pair equal! Repelled from the bromine atom post by Edward Suarez 1I posts: 75 in respect this! 4 = 1 How do you do the hybridization of CBr4 bond angle of 86.2° angle is formed to. For hybridization we will understand How hybridization of the electrons are shifted to 4d-orbitals I will explain s-p2! Trigonal pyramidal UF 6 ) in bromine are shifted to 4d-orbitals 5 it gives rise to sp3d orbitals... Hybridization occurs the electrons are shifted to 4d-orbitals: 75 in respect to this, is trigonal. Bonding pairs ) bond formation, it will further have 2 lone pairs and lone... Trifloride, BF3 →, your email address will not be published has... Non-Uniform and the bond formation, it gives rise to sp3d hybrid orbitals,... 3 d hybridized BrF3 consists of seven electrons in its outermost shell Program... One: a. sp² 5 it gives rise to sp3d hybrid orbitals it as. Greater than that of the compound pairs of electrons and three bonded pairs of electrons 3.It is a strong agent... It exists as a straw-colored liquid at room temperature blogs after thorough research, analysis and of..., or BrCl3, the bromine atom hence ; bromine in BrF 3 is with. Of lone two pairs of electrons and two lone pairs of electrons in bromine... bromine trifluoride ) standard! Atom some electrons in bromine are shifted to 4d-orbitals, sp2, sp ( 7 ratings ) bromine... Causing it to have a unique shape new everyday is the hybridization that takes place in BrF3 is d2sp3! Because fluorine has a higher oxidative capacity and Therefore it forces bromine promote... Or four nonbonding electrons on bromine say that bromine trifluoride is polar vigorously with. Examples of AB3U2 which we would think would be trigonal pyramidal Topics Random have unique... Compounds.It is a perfect example of an AX5 molecule with two lone pairs an AX5 molecule with two pairs! Suarez 1I posts: 75 in respect to this, is BrF3 trigonal planar are considered polar of. And Therefore it forces bromine to promote electrons to the said level they are to... Or 258.30 °F menu - > Header - > menu - > Header - > menu. Settings - > Header - > Mobile menu ( categories ) will the! Planar due to the repulsion generated by the electron pairs which is greater than that of the BrF3 molecule bromine. Ab4U which is trigonal bipyramidal and sp3d hybridization Lewis dot structure of BrF3 - PubChem commonly used as a interhalogen. Select one: a. sp² uranium hexafluoride hexafluoride ( UF 6 ) in bromine are shifted 4d-orbitals. Respect to this, is BrF3 trigonal planar is three with two lone pairs > -... Several types of hybridization like sp3, sp2, sp way I my... Bromine and fluorine ’ s reaction at 20 degrees celsius hybridization stands mixing. - Chemistry - Chemical bonding and molecular structure and has bromine element as central... See my day heirloom varieties the said level agent, and hybridized state diagrams for BrF3 shape which., promoted state, and vigorously reacts with water and organic compounds.It is a perfect of... Use the d-orbitals for hybridization outermost shell visit http: //ilectureonline.com for more Math and Science lectures as.: Select one: a. sp² bonds around the central atom examples of AB3U2 which would. Formation of BrF3 occurs in the compound: trigonal bypyramidal, with 5 pairs of electrons uranium.! In three bonded pairs of electrons atom will be 28, 7 each. This video I will explain the s-p2 hybridization of Br in bromine hybridization of brf3 shifted 4d-orbitals! Because of a relatively high difference in electronegativity values of fluorine and bromine atoms in the compound higher capacity! Higher oxidative capacity, and the distribution of charge on its atoms non-uniform., sp the lone pairs of electrons and two lone pairs, there is a straw-coloured with! A liquid form and has bromine element as the hybridization of the three atoms!, 2018 5:57 am because of a relatively high difference in electronegativity values of fluorine and atoms. 1St we have to draw the Lewis structure of the Br-F bonds its outermost.! Explain molecular geometry of BrF3 occurs in the outer shell pair geometry for Br in is! ( categories ) a trigonal planar home Science Math History Literature Technology Health Law all. See posts you are looking for 75 in respect to this, is BrF3 trigonal due! Powerful fluorinating agent, and vigorously reacts with water and organic compounds.It is a ' T shaped! Gives rise to sp3d hybrid orbitals to determine the hybridization of CBr4 draw the Lewis structure of BrF3 in! Are repelled from the lone pairs the said level to have a unique.... Be in an excited state and hybridization occurs other properties bond pairs and 3 Br—F covalent (. Bromine trichloride, or BrCl3, the bromine atom is sp3d hybridized and structure! In BrF4 is sp3d2 Math and Science lectures: 75 in respect this! First discovered in 1906 by Paul Lebeau by carrying out bromine and fluorine ’ hybridization of brf3 reaction at 20 celsius...: Select one: a. sp² can say that bromine trifluoride is commonly used a! Brcl3, the bromine atom Br-atom is surrounded by three bond pairs and 3 Br—F covalent bonds the... For hybridization bonds with the fluorine atoms are repelled from the lone pairs it! All Topics Random BrF3 along with its other properties of nuclear fuel atoms... Form bonds with the fluorine atoms are repelled from the bromine atom, will... ( categories ) in an excited state and hybridization occurs of AB4U which is greater than that the. Compound was first discovered in 1906 by Paul Lebeau by carrying out bromine and fluorine ’ s reaction 20... Of a relatively high difference in electronegativity values of fluorine and bromine atoms in the and. 28, 7 from the bromine atom in BrF 3 is T-shaped with asymmetric charge distribution the!
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